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ReviewFebruary 27, 2025

Dual-Atom Catalysts for the Hydrogen Evolution Reaction

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Hao Sun

Hao Sun

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Linyang Li

Linyang Li

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Xin Li

Xin Li

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Junhe Yang

Junhe Yang

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Yuepeng Pang

Yuepeng Pang

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Shiyou Zheng*

Shiyou Zheng

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

*Email: [email protected]

ACS Applied Energy Materials

Cite this: ACS Appl. Energy Mater. 2025, 8, 6

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Published February 27, 2025

review-article

Copyright © 2025 American Chemical Society

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Abstract

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Dual-atom catalysts (DACs) have gained great attention as highly efficient materials for the hydrogen evolution reaction (HER) due to their synergistic dual-site effects and high atomic utilization. This review explores how microenvironmental regulation, including electronic structure optimization and coordination design, influences DAC performance. Both homonuclear and heteronuclear types of DACs are analyzed in detail in terms of their site interactions and structural configurations. Moreover, recent advancements of DACs in HER applications under various pH conditions are discussed, highlighting their enhanced catalytic activity and mechanism. Despite challenges in synthesis and characterization, DACs represent a promising frontier for developing efficient HER catalysts and offer guidance for future research and scalable applications.

ACS Publications

Copyright © 2025 American Chemical Society

Cited By

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This article is cited by 2 publications.

Rui Fan, Guojing Yu, Weijie Ren, Ye Xiong. Double Molten Salt Engineered Highly Exposed Ni3Fe Honeycomb Nanospheres with Defect-Rich N/S Codoped Hierarchical Bamboo Carbon for Efficient Oxygen Evolution. ACS Applied Energy Materials 2025, 8 (11) , 7614-7621. https://doi.org/10.1021/acsaem.5c00873Yuanyuan Wang, Chunmei Tang, Ting Xiao, Fujian Xiong, Xiaofeng Zhou, Kaixiao Zhang, Jiangfeng Gong. High-throughput screening of trimetallic dual-atom alloy catalysts for electrocatalytic nitrate reduction to ammonia. Journal of Energy Chemistry 2025, 110 , 728-739. https://doi.org/10.1016/j.jechem.2025.07.015

ACS Applied Energy Materials

Cite this: ACS Appl. Energy Mater. 2025, 8, 6

Click to copy citationCitation copied!

Published February 27, 2025

Copyright © 2025 American Chemical Society

Article Views

921

Altmetric

-

Learn about these metrics

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

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